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Asphaltene in Crude Oils: A Concentrated Theoretical-Practical Course |
Instructors: Charles F. Alcocer, Ph.D.
Course Description: This course discusses in depth all the emerging laboratory and field technologies. related to asphaltene. The course considers Near Infrared Spectroscopy laboratory Technology, Spectrum/ Electromagnetic principles and theory, 3-D P-T- Composition diagrams of flocculation curves for asphaltene, Magnetic and electromagnetic principles, theory and design of magnetic and electromagnetic devices applied to petroleum industry, Microbial methods field design and laboratory implementation. Attention is given to mathematical models to predict asphaltene deposition. This course discusses the latest results in characterization of asphaltene. Special attention is given to the description, construction and interpretation of P-T-ADE envelopes to establish production strategies to produce asphaltenic crude oil and avoid or minimize formation damage thought asphaltene control deposition. A review in depth of the conventional methods to control asphaltene is included. Coating technology and modern field applications cases are included in the course. A comparative study of Methods/Technologies: Advantages and disadvantages. is discussed in details. Laboratory studies and Field cases are part of the course. A workshop during the last day review in depth all the material on asphaltene in practical manner for immediate field applications.
Target Audience: This course is designed for Pipeline, Production, Reservoir Engineers and theirs Supervisors, Chemical Engineers associated with the oil industry, Geophysical and Technical field personnel and Service Companies representatives that wish to obtain or increase understanding on asphaltene problems associated to field operations
Course Contents:
First day:
I. Introduction
Introduction and scope of the course
Brief History of asphaltene problems in crude oil production
Economic Impact of the Problem
Economic History Case
Significant Breakthroughs in the field of asphaltene treatments
Initial Test for Pre-evaluation.
II. Producing Asphaltene in Crude Oils: Problems And Solutions
Introduction
Asphaltene composition: The molecular nature of petroleum asphaltene
Asphaltene structures: Discussion and competition
Thermodynamic Colloidal Model for asphaltene
Chemical concepts of Colloids and phases, Solution, and suspension applied to the understanding of asphaltene.
Concept of Micelle, Peptization and depeptization process in asphaltene
Conceptual Molecular-Thermodynamic Model for asphaltene
Mechanisms of flocculation and deposition for asphaltene
8.1 Molecular diffusion as main lateral mechanism of transport of asphaltene
8.2 Shear Dispersion
8.3 Brownian Diffusion
8.4 Gravity settling of Asphaltene
8.5 Practical application of these concepts to field problems related to asphaltene
Influence of temperature, composition and pressure on asphaltene flocculation.
Second Day:
Formation damage by Asphaltene Flocculation, Deposition and Plugging.
Formation Change of Wettability by asphaltene Deposition and Flocculation.
State of the art sampling technology for laboratory analysis of asphaltene
P-T ADE envelops: Description, Construction and interpretation
Production Strategies to produce Asphaltenic crude oil base on P-T-ADE envelops
Combination with Production optimization to establish production strategies: Discussion, practice and competition
Formation Damage prevention through control deposition
Absorbance optical concept and Absorbance behavior vs. time in asphaltenic crudes
Modern Asphaltene stability method/ laboratory procedure.
UV method to determine asphaltene stability (field application)
Experimental equipment (UV) for atmospheric experiments.
Experimental equipment for elevated pressure & elevated temperatures
Asphaltene precipitation from heavy-medium oils by gas injection-miscible and/or inmiscible flooding.
Conventional Methods to control Asphaltene.
Microbial and Magnetic/Electromagnetic methods for control and prevention of deposition of asphaltene. Practice/discussion and competition
Third Day:
Effect of diluent and carbon dioxide on asphaltene and flocculation in heavy solution
Diagram of stabilization power of chemicals
Comparative study of NIR curve interpretation with P-T-ADE curves
Introduction to NIR Paraffin/Asphaltene Crystallization/Flocculation curves to diagnose asphaltene problems to establish strategies for reservoir exploitation.
Selection and Optimization of Chemical Injection by Using diagrams of stabilization Power.
Boscan/Panuco Crude Phenomenon/ Research results and filed applications
New formation treatment method to control asphaltene deposition based on stability method.
A conceptually Review Thermodynamic-Molecular and Thermodynamic-Colloidal models to predict asphaltene deposition
Asphaltene and Paraffin case histories ( Problem -Solutions)
Monophasic sampling technology for live-reservoir sampling collection
Design and specification and quality control of Permanent magnets/Electromagnetic devices applied to oil industry.
Fourth Day:
III New Technology to Control/Prevent Asphaltene
Compatibility Techniques in Reservoir previous to Stimulation.
Field Problems related with Asphaltenic reservoir exploitation
Microbial Control of Asphaltene at reservoir level
Influence of Magnetic and Electromagnetic field on Asphaltene
Review magnetic and electromagnetic application
Magneto-Hydro-Dynamic principle and research associated to the principle
Lorenz's Law applied to Petroleum Engineering
Aggregate/disaggregated theory applied to magnetic/eletromagnetic devices
Analysis of Laboratory results with magnetic/electromagnetic devices
Field Application of magnetic/electromagnetic devices
Quality Control in Microbial and Magnetic/Electromagnetic field application
Final discussion and conclusions on new methods to control/prevent paraffin
General discussion on asphaltene and conclusions
Final technical competition on Asphaltene.
Fifth Day:
IV. Asphaltene Workshop
This workshop will be conducted during the 5th day of the course.
A. Objectives of the workshop are as follows:
Review and extend course material or specific points based on student request
Further group discussion on specific topic related to the course
Presentation of field production/reservoir problems by the participants/students
Establish and suggest work plans to be implemented in field operation
Discuss team work done by other companies in other countries in relation to problems of asphaltene
Discuss student's specific field problems and methods that have been applied to solve paraffin/asphaltene/scale deposition and have failed
Others.
B. Final Test Evaluation.
Additional equipment needed: Computer for Power point projection, Slide Projector, Overhead Projector, Vinyl Blackboard and VCR
LENGHT: 5 DAYS ( 40 Hrs)